This Way:
XML:
<Employees>
<Details>
<Name>
John
</Name>
</Details>
<Details>
<Name>
Smith
</Name>
</Details>
<Details>
<Name>
Micheal
</Name>
</Details>
</Employees>
HTML:
<form id="form1" runat="server">
<div>
Name of Emplyees
<br />
<asp:Label ID="lblName" Text="" runat="server" />
</div>
</form>
C#:
protected void Page_Load(object sender, EventArgs e)
{
if (!this.IsPostBack)
{
using (DataSet ds = new DataSet())
{
ds.ReadXml(Server.MapPath("XMLFile1.xml"));
for (int i = 0; i < ds.Tables[0].Rows.Count; i++)
{
lblName.Text += ds.Tables["Details"].Rows[i]["Name"].ToString() + "<br />";
}
}
}
}
OutPut:

Thank You.