Hi PRA
Please refer below sample.
Database
For this example I have used of Northwind database that you can download using the link given below.
Download Northwind Database
HTML
<asp:GridView ID="gvCustomers" runat="server" AutoGenerateColumns="false">
    <Columns>
        <asp:BoundField DataField="Country" HeaderText="Country" />
        <asp:BoundField DataField="Total" HeaderText="Total" />
    </Columns>
</asp:GridView>
Namespace
C#
using AjaxSamplesModel;
VB.Net
Imports AjaxSamplesModel
Code
C#
protected void Page_Load(object sender, EventArgs e)
{
    if (!this.IsPostBack)
    {
        this.BindGrid();
    }
}
private void BindGrid()
{
    using (AjaxSamplesEntities entities = new AjaxSamplesEntities())
    {
        var result = (from customer in entities.Customers
                        group customer by customer.Country into g
                        where g.Count() > 5
                        select new
                        {
                            Country = g.Key,
                            Total = g.Count()
                        }).ToList();
        gvCustomers.DataSource = result;
        gvCustomers.DataBind();
    }
}
VB.Net
Public Sub Page_Load(sender As Object, e As EventArgs) Handles Me.Load
    If Not Me.IsPostBack Then
        Me.BindGrid()
    End If
End Sub
Private Sub BindGrid()
    Using entities As AjaxSamplesEntities = New AjaxSamplesEntities()
        Dim result = (From customer In entities.Customers
                        Group customer By customer.Country Into cGroup = Group, Count()
                        Where cGroup.Count() > 5
                        Select New With
                        {
                            .Country = Country,
                            .Total = cGroup.Count()
                        }).ToList()
        gvCustomers.DataSource = result
        gvCustomers.DataBind()
    End Using
End Sub