ASP.Net GridView Printing with Paging and Page Break with hiding Column in ASP.Net

Here I have created sample that will help you out.

HTML

<div>
    <asp:GridView ID="GridView1" runat="server" AutoGenerateColumns="false" Font-Names="Arial"
        Font-Size="11pt" AlternatingRowStyle-BackColor="#C2D69B" HeaderStyle-BackColor="green"
        AllowPaging="true" OnPageIndexChanging="OnPaging" DataKeyNames="CustomerID">
        <Columns>
            <asp:TemplateField>
                <ItemTemplate>
                    <asp:CheckBox ID="chk" runat="server" />
                </ItemTemplate>
            </asp:TemplateField>
            <asp:BoundField ItemStyle-Width="150px" DataField="CustomerID" HeaderText="CustomerID" />
            <asp:BoundField ItemStyle-Width="150px" DataField="City" HeaderText="City" />
            <asp:BoundField ItemStyle-Width="150px" DataField="PostalCode" HeaderText="PostalCode" />
        </Columns>
    </asp:GridView>
    <br />
    <asp:Button ID="btnPrintAll" runat="server" Text="Print All Pages" OnClick="PrintAllPages" />
    <asp:Button ID="btnPrintCurrent" runat="server" Text="Print Current Page" OnClick="PrintCurrentPage" />
</div>

C#

protected void Page_Load(object sender, EventArgs e)
{
    Response.Cache.SetCacheability(HttpCacheability.NoCache);
    BindGrid();
}

private void BindGrid()
{
    string strQuery = "select CustomerID,City,PostalCode" +
        " from customers";
    DataTable dt = new DataTable();
    String strConnString = System.Configuration.ConfigurationManager
                .ConnectionStrings["conString"].ConnectionString;
    SqlConnection con = new SqlConnection(strConnString);
    SqlDataAdapter sda = new SqlDataAdapter();
    SqlCommand cmd = new SqlCommand(strQuery);
    cmd.CommandType = CommandType.Text;
    cmd.Connection = con;
    try
    {
        con.Open();
        sda.SelectCommand = cmd;
        sda.Fill(dt);
        GridView1.DataSource = dt;
        GridView1.DataBind();
    }
    catch (Exception ex)
    {
        throw ex;
    }
    finally
    {
        con.Close();
        sda.Dispose();
        con.Dispose();
    }
}

public override void VerifyRenderingInServerForm(Control control)
{
    /*Verifies that the control is rendered */
}

protected void OnPaging(object sender, GridViewPageEventArgs e)
{
    GridView1.PageIndex = e.NewPageIndex;
    GridView1.DataBind();
}

protected void PrintCurrentPage(object sender, EventArgs e)
{
    GridView1.PagerSettings.Visible = false;
    GridView1.DataBind();
    GridView1.Attributes["style"] = "border-collapse:separate";
    foreach (GridViewRow row in GridView1.Rows)
    {
        if (row.RowIndex % 10 == 0 && row.RowIndex != 0)
        {
            row.Attributes["style"] = "page-break-after:always;";
        }
    }
    GridView1.Columns[0].Visible = false;
    StringWriter sw = new StringWriter();
    HtmlTextWriter hw = new HtmlTextWriter(sw);
    GridView1.RenderControl(hw);
    string gridHTML = sw.ToString().Replace("\"", "'")
        .Replace(System.Environment.NewLine, "");
    StringBuilder sb = new StringBuilder();
    sb.Append("<script type = 'text/javascript'>");
    sb.Append("window.onload = new function(){");
    sb.Append("var printWin = window.open('', '', 'left=0");
    sb.Append(",top=0,width=1000,height=600,status=0');");
    sb.Append("printWin.document.write(\"");
    sb.Append(gridHTML);
    sb.Append("\");");
    sb.Append("printWin.document.close();");
    sb.Append("printWin.focus();");
    sb.Append("printWin.print();");
    sb.Append("printWin.close();};");
    sb.Append("</script>");
    ClientScript.RegisterStartupScript(this.GetType(), "GridPrint", sb.ToString());
    GridView1.PagerSettings.Visible = true;
    GridView1.DataBind();
    GridView1.Columns[0].Visible = true;
}

protected void PrintAllPages(object sender, EventArgs e)
{
    GridView1.AllowPaging = false;
    GridView1.DataBind();
    GridView1.Attributes["style"] = "border-collapse:separate";
    foreach (GridViewRow row in GridView1.Rows)
    {
        if (row.RowIndex % 10 == 0 && row.RowIndex != 0)
        {
            row.Attributes["style"] = "page-break-after:always;";
        }
    }
    GridView1.Columns[0].Visible = false;
    StringWriter sw = new StringWriter();
    HtmlTextWriter hw = new HtmlTextWriter(sw);
    GridView1.RenderControl(hw);
    string gridHTML = sw.ToString().Replace("\"", "'")
        .Replace(System.Environment.NewLine, "");
    StringBuilder sb = new StringBuilder();
    sb.Append("<script type = 'text/javascript'>");
    sb.Append("window.onload = new function(){");
    sb.Append("var printWin = window.open('', '', 'left=0");
    sb.Append(",top=0,width=1000,height=600,status=0');");
    sb.Append("printWin.document.write(\"");
    sb.Append(gridHTML);
    sb.Append("\");");
    sb.Append("printWin.document.close();");
    sb.Append("printWin.focus();");
    sb.Append("printWin.print();");
    sb.Append("printWin.close();};");
    sb.Append("</script>");
    ClientScript.RegisterStartupScript(this.GetType(), "GridPrint", sb.ToString());
    GridView1.AllowPaging = true;
    GridView1.DataBind();
    GridView1.Columns[0].Visible = true;
}

Screenshot