Hi,
please refer below code.
C#
string connectionString = ConfigurationManager.ConnectionStrings["ConString"].ConnectionString;
Web.Config
<configuration>
<connectionStrings>
<add name="ConString" connectionString="Data Source=Mudassar-PC\SQL2005;Initial Catalog=Northwind;Integrated Security=true"/>
</connectionStrings>
</configuration>
Note : Connection string name must be same in C# code as well as web.config file.