The Code which you pasted in that sender is GridView not CommandField.
You need to use RowCommand Or LinkButton Onclick Eevent
Refer this
 HTML 
<asp:GridView ID="GridView1" HeaderStyle-BackColor="#3AC0F2" HeaderStyle-ForeColor="White"
    runat="server" AutoGenerateColumns="false">
    <Columns>
        <asp:BoundField DataField="Id" HeaderText="Id" ItemStyle-Width="30" />
        <asp:BoundField DataField="Name" HeaderText="Name" ItemStyle-Width="150" />
        <asp:BoundField DataField="Country" HeaderText="Country" ItemStyle-Width="150" />
        <asp:TemplateField>
            <ItemTemplate>
                <asp:LinkButton ID="LinkButton1" Text="Select" OnClick="Select" CommandArgument="View profile"
                    runat="server" />
            </ItemTemplate>
        </asp:TemplateField>
    </Columns>
</asp:GridView>
 C#
protected void Page_Load(object sender, EventArgs e)
{
    if (!this.IsPostBack)
    {
        DataTable dt = new DataTable();
        dt.Columns.AddRange(new DataColumn[3] { new DataColumn("Id", typeof(int)),
                        new DataColumn("Name", typeof(string)),
                        new DataColumn("Country",typeof(string)) });
        dt.Rows.Add(1, "John Hammond", "United States");
        dt.Rows.Add(2, "Mudassar Khan", "India");
        dt.Rows.Add(3, "Suzanne Mathews", "France");
        dt.Rows.Add(4, "Robert Schidner", "Russia");
        GridView1.DataSource = dt;
        GridView1.DataBind();
    }
}
protected void Select(object sender, EventArgs e)
{
    LinkButton btn = (sender as LinkButton);
    GridViewRow row = btn.NamingContainer as GridViewRow;
    if (btn.CommandArgument.Equals("View profile"))
    {
        //Session["conID"] = (row.FindControl("Label6") as Label).Text;
        Response.RedirectPermanent("~/TrainersDetails.aspx", false);
    }
    else
    {
        // Session["conID"] = (row.FindControl("Label6") as Label).Text;
        Response.RedirectPermanent("~/Marketing/Block Trainers.aspx");
    }
}
 Also Check the ID of Label in the GridView
	
Session["conID"] = (row.FindControl("Label6") as Label).Text;