ASP.Net Email Error: Client does not have permission to submit mail to this server. The server response was: 5.5.1 STARTTLS may not be repeated

I was trying to send email to some one from my web page but i got some error ,following is code that i am using

MailMessage mymailmessage = newMailMessage();

mymailmessage.From =newMailAddress(TextBox2.Text);

mymailmessage.To.Add(supersoft.pc13890@gmail.com);

mymailmessage.Body = TextBox3.Text;

SmtpClient smclient = newSmtpClient("smtp.gmail.com");

smclient.Port = 587; 

smclient.Credentials =new System.Net.NetworkCredential(TextBox2.Text, TextBox1.Text);

smclient.EnableSsl =true;

smclient.Send(mymailmessage);

error is: Client does not have permission to submit mail to this server. The server response was: 5.5.1 STARTTLS may not be repeated. ha10sm52948117pbc.23 - gsmtp

help me experts