Hi  Waghmare,
Refer the Below Sample for your reference.
<html xmlns="http://www.w3.org/1999/xhtml">
<head runat="server">
    <title></title>
    <script type="text/javascript" src="http://ajax.googleapis.com/ajax/libs/jquery/1.8.3/jquery.min.js"></script>
    <link rel="stylesheet" type="text/css" href="http://cdnjs.cloudflare.com/ajax/libs/twitter-bootstrap/3.0.3/css/bootstrap.min.css" />
    <script type="text/javascript" src="http://cdnjs.cloudflare.com/ajax/libs/twitter-bootstrap/3.0.3/js/bootstrap.min.js"></script>
    <link rel="stylesheet" type="text/css" href="https://cdnjs.cloudflare.com/ajax/libs/bootstrap-select/1.5.4/bootstrap-select.css" />
    <script type="text/javascript" src="https://cdnjs.cloudflare.com/ajax/libs/bootstrap-select/1.5.4/bootstrap-select.js"></script>
    <script type="text/javascript">
        $(function () {
            $('#ddlFruits').selectpicker({
                style: 'btn-info',
                size: 4
            });
        });       
    </script>
</head>
<body>
    <form id="form1" runat="server">
    <div class="row">
        <div class="col-md-2">
            <asp:DropDownList ID="ddlFruits" runat="server">
                <asp:ListItem Text="Please Select" Value="0"></asp:ListItem>
                <asp:ListItem Text="Mango" Value="1" />
                <asp:ListItem Text="Apple" Value="2" />
                <asp:ListItem Text="Banana" Value="3" />
                <asp:ListItem Text="Guava" Value="4" />
                <asp:ListItem Text="Orange" Value="5" />
            </asp:DropDownList>
        </div>
        <div class="col-md-2">
            <asp:RequiredFieldValidator ID="RequiredFieldValidator1" ControlToValidate="ddlFruits"
                runat="server" InitialValue="0" ErrorMessage="Required"></asp:RequiredFieldValidator>
        </div>
        <div class="col-md-2">
            <asp:Button ID="Button1" Text="Submit" runat="server" OnClick="Submit" class="btn btn-primary" />
        </div>
    </div>
    </form>
</body>
</html>
C#
protected void Submit(object sender, EventArgs e)
{
    string selectedvalue = string.Format("Selected Value: {0} and Selected Text: {1}", ddlFruits.SelectedValue, ddlFruits.SelectedItem.Text);
    ClientScript.RegisterClientScriptBlock(this.GetType(), "", "alert('" + selectedvalue + "')", true);
}
VB.Net
Protected Sub Submit(sender As Object, e As EventArgs)
	Dim selectedvalue As String = String.Format("Selected Value: {0} and Selected Text: {1}", ddlFruits.SelectedValue, ddlFruits.SelectedItem.Text)
	ClientScript.RegisterClientScriptBlock(Me.[GetType](), "", (Convert.ToString("alert('") & selectedvalue) + "')", True)
End Sub
Screeshot
